Antiphase Boundaries and Twins Associated with Ordering of Indium Vacancies in β‐In2S3

J. van Landuyt; S. Amelinckx

doi:10.1002/pssb.19690310219

Antiphase Boundaries and Twins Associated with Ordering of Indium Vacancies in β‐In₂S₃

J. van Landuyt, S. Amelinckx

Research output › peer-review

Abstract

β‐Indium sulfide crystals have been studied by electron microscopy and electron diffraction. From an analysis of the defective spinel structure, different types of ordering defects are predicted. Ordering twins and two types of antiphase domains have been observed, and their analysis is in complete agreement with the proposed models. Heating experiments enabled a distinction to be made between the defects associated with the tetrahedrally surrounded cations and those in octahedral sites. A mechanism is proposed for the two transitions previously observed in this material: The transition at 420 °C is attributed to the disordering of tetrahedral cations, whereas the transition at 750 °C is associated with the disordering of the octahedrally surrounded cations.

Original language	English
Pages (from-to)	589-600
Number of pages	12
Journal	Physica Status Solidi (B)
Volume	31
Issue number	2
DOIs	https://doi.org/10.1002/pssb.19690310219
State	Published - 1969

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics

Access to Document

10.1002/pssb.19690310219

Cite this

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title = "Antiphase Boundaries and Twins Associated with Ordering of Indium Vacancies in β‐In2S3",

abstract = "β‐Indium sulfide crystals have been studied by electron microscopy and electron diffraction. From an analysis of the defective spinel structure, different types of ordering defects are predicted. Ordering twins and two types of antiphase domains have been observed, and their analysis is in complete agreement with the proposed models. Heating experiments enabled a distinction to be made between the defects associated with the tetrahedrally surrounded cations and those in octahedral sites. A mechanism is proposed for the two transitions previously observed in this material: The transition at 420 °C is attributed to the disordering of tetrahedral cations, whereas the transition at 750 °C is associated with the disordering of the octahedrally surrounded cations.",

author = "{van Landuyt}, J. and S. Amelinckx",

year = "1969",

doi = "10.1002/pssb.19690310219",

language = "English",

volume = "31",

pages = "589--600",

journal = "Physica Status Solidi (B)",

issn = "0370-1972",

publisher = "Wiley - John Wiley & Sons, Ltd",

number = "2",

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T1 - Antiphase Boundaries and Twins Associated with Ordering of Indium Vacancies in β‐In2S3

AU - van Landuyt, J.

AU - Amelinckx, S.

PY - 1969

Y1 - 1969

N2 - β‐Indium sulfide crystals have been studied by electron microscopy and electron diffraction. From an analysis of the defective spinel structure, different types of ordering defects are predicted. Ordering twins and two types of antiphase domains have been observed, and their analysis is in complete agreement with the proposed models. Heating experiments enabled a distinction to be made between the defects associated with the tetrahedrally surrounded cations and those in octahedral sites. A mechanism is proposed for the two transitions previously observed in this material: The transition at 420 °C is attributed to the disordering of tetrahedral cations, whereas the transition at 750 °C is associated with the disordering of the octahedrally surrounded cations.

AB - β‐Indium sulfide crystals have been studied by electron microscopy and electron diffraction. From an analysis of the defective spinel structure, different types of ordering defects are predicted. Ordering twins and two types of antiphase domains have been observed, and their analysis is in complete agreement with the proposed models. Heating experiments enabled a distinction to be made between the defects associated with the tetrahedrally surrounded cations and those in octahedral sites. A mechanism is proposed for the two transitions previously observed in this material: The transition at 420 °C is attributed to the disordering of tetrahedral cations, whereas the transition at 750 °C is associated with the disordering of the octahedrally surrounded cations.

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U2 - 10.1002/pssb.19690310219

DO - 10.1002/pssb.19690310219

M3 - Article

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SN - 0370-1972

VL - 31

SP - 589

EP - 600

JO - Physica Status Solidi (B)

JF - Physica Status Solidi (B)

IS - 2

ER -