Chemical engineering assessment of the thermochemical cycle mark 9

M. Hoogstoel; W. R.A. Goossens; A. Francesconi; L. H. Baetslé

doi:10.1016/0360-3199(79)90026-0

Chemical engineering assessment of the thermochemical cycle mark 9

M. Hoogstoel, W. R.A. Goossens, A. Francesconi, L. H. Baetslé

Research output › peer-review

Abstract

The thermochemical cycles of the FeCl family are reviewed with special emphasis on the changes brought to the reaction sequence. The chemical equilibria involved in the hydrolysis, chlorination, decomposition and oxygen removal steps of the MARK 9, MARK 14 cycles are discussed in detail and resulting data are used in an engineering flow sheet of the MARK 9 cycle. The hydrolysis of FeCl₂ which is common to many FeCl cycles was examined from kinetics point of view and detailed mass and energy balances are given for different types of reaction conditions. The thermal efficiency is the limiting factor of this type of thermochemical cycle.

Original language	English
Pages (from-to)	211-222
Number of pages	12
Journal	International Journal of Hydrogen Energy
Volume	4
Issue number	3
DOIs	https://doi.org/10.1016/0360-3199(79)90026-0
State	Published - 1979

ASJC Scopus subject areas

Renewable Energy, Sustainability and the Environment
Fuel Technology
Condensed Matter Physics
Energy Engineering and Power Technology

Access to Document

10.1016/0360-3199(79)90026-0

Cite this

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abstract = "The thermochemical cycles of the FeCl family are reviewed with special emphasis on the changes brought to the reaction sequence. The chemical equilibria involved in the hydrolysis, chlorination, decomposition and oxygen removal steps of the MARK 9, MARK 14 cycles are discussed in detail and resulting data are used in an engineering flow sheet of the MARK 9 cycle. The hydrolysis of FeCl2 which is common to many FeCl cycles was examined from kinetics point of view and detailed mass and energy balances are given for different types of reaction conditions. The thermal efficiency is the limiting factor of this type of thermochemical cycle.",

author = "M. Hoogstoel and Goossens, {W. R.A.} and A. Francesconi and Baetsl{\'e}, {L. H.}",

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AU - Francesconi, A.

AU - Baetslé, L. H.

PY - 1979

Y1 - 1979

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AB - The thermochemical cycles of the FeCl family are reviewed with special emphasis on the changes brought to the reaction sequence. The chemical equilibria involved in the hydrolysis, chlorination, decomposition and oxygen removal steps of the MARK 9, MARK 14 cycles are discussed in detail and resulting data are used in an engineering flow sheet of the MARK 9 cycle. The hydrolysis of FeCl2 which is common to many FeCl cycles was examined from kinetics point of view and detailed mass and energy balances are given for different types of reaction conditions. The thermal efficiency is the limiting factor of this type of thermochemical cycle.

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