Electrochemical Measurement of Sieverts’ Constant and Solubility of Oxygen in LBE at 598–748 K

Jun Lim; Gabriele Manfredi; Alessandro Marino; Kristof Gladinez; Alexander Aerts; Alexander Aerts

doi:10.1149/2.0231712jes

Electrochemical Measurement of Sieverts’ Constant and Solubility of Oxygen in LBE at 598–748 K

Jun Lim, Gabriele Manfredi, Alessandro Marino, Kristof Gladinez, Alexander Aerts, Alexander Aerts

Conditioning and Chemistry Programme

Research output › peer-review

Abstract

The solubility of oxygen in liquid lead bismuth eutectic (LBE) was determined by using electrochemical methods. The oxygen partial pressure in oxygen saturated LBE was measured from 475 to 724 K by using an oxygen sensor comprised of yttria partially stabilized zirconia and air/LSM (Lanthanum strontium manganite) reference electrode. Sieverts’ constant of the dissolved oxygen in LBE was measured from 598 to 748 K by coulometric titration method using the oxygen sensor. The measured oxygen partial pressure in oxygen saturated LBE (PO2(LBE−PbO) in bar) and Sieverts’ constant of dissolved oxygen in LBE (k for 1 wt.% standard state) are given by log PO2(LBE−PbO) = 11.52 − 22996/T (475-724 K), log k = 3.12 − 7072/T (598-748 K) respectively. Combining the measured data, the oxygen solubility in LBE (CO,S in wt.%) was derived and it is given by logCO,S = 2.64 − 4426/T (598-724 K).

Original language	English
Pages (from-to)	H743-H747
Number of pages	4
Journal	Journal of The Electrochemical Society
Volume	164
Issue number	12
DOIs	https://doi.org/10.1149/2.0231712jes
State	Published - 10 Aug 2017

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10.1149/2.0231712jes

Cite this

@article{add47f47b7564996b6692d5bcf6a774c,

title = "Electrochemical Measurement of Sieverts{\textquoteright} Constant and Solubility of Oxygen in LBE at 598–748 K",

abstract = "The solubility of oxygen in liquid lead bismuth eutectic (LBE) was determined by using electrochemical methods. The oxygen partial pressure in oxygen saturated LBE was measured from 475 to 724 K by using an oxygen sensor comprised of yttria partially stabilized zirconia and air/LSM (Lanthanum strontium manganite) reference electrode. Sieverts{\textquoteright} constant of the dissolved oxygen in LBE was measured from 598 to 748 K by coulometric titration method using the oxygen sensor. The measured oxygen partial pressure in oxygen saturated LBE (PO2(LBE−PbO) in bar) and Sieverts{\textquoteright} constant of dissolved oxygen in LBE (k for 1 wt.% standard state) are given by log PO2(LBE−PbO) = 11.52 − 22996/T (475-724 K), log k = 3.12 − 7072/T (598-748 K) respectively. Combining the measured data, the oxygen solubility in LBE (CO,S in wt.%) was derived and it is given by logCO,S = 2.64 − 4426/T (598-724 K).",

keywords = "LBE, oxygen solubility",

author = "Jun Lim and Gabriele Manfredi and Alessandro Marino and Kristof Gladinez and Alexander Aerts and Alexander Aerts",

note = "Score=10",

year = "2017",

month = aug,

day = "10",

doi = "10.1149/2.0231712jes",

language = "English",

volume = "164",

pages = "H743--H747",

journal = "Journal of The Electrochemical Society",

issn = "0013-4651",

publisher = "ECS - The Electrochemical Society",

number = "12",

}

TY - JOUR

T1 - Electrochemical Measurement of Sieverts’ Constant and Solubility of Oxygen in LBE at 598–748 K

AU - Lim, Jun

AU - Manfredi, Gabriele

AU - Marino, Alessandro

AU - Gladinez, Kristof

AU - Aerts, Alexander

A2 - Aerts, Alexander

N1 - Score=10

PY - 2017/8/10

Y1 - 2017/8/10

N2 - The solubility of oxygen in liquid lead bismuth eutectic (LBE) was determined by using electrochemical methods. The oxygen partial pressure in oxygen saturated LBE was measured from 475 to 724 K by using an oxygen sensor comprised of yttria partially stabilized zirconia and air/LSM (Lanthanum strontium manganite) reference electrode. Sieverts’ constant of the dissolved oxygen in LBE was measured from 598 to 748 K by coulometric titration method using the oxygen sensor. The measured oxygen partial pressure in oxygen saturated LBE (PO2(LBE−PbO) in bar) and Sieverts’ constant of dissolved oxygen in LBE (k for 1 wt.% standard state) are given by log PO2(LBE−PbO) = 11.52 − 22996/T (475-724 K), log k = 3.12 − 7072/T (598-748 K) respectively. Combining the measured data, the oxygen solubility in LBE (CO,S in wt.%) was derived and it is given by logCO,S = 2.64 − 4426/T (598-724 K).

AB - The solubility of oxygen in liquid lead bismuth eutectic (LBE) was determined by using electrochemical methods. The oxygen partial pressure in oxygen saturated LBE was measured from 475 to 724 K by using an oxygen sensor comprised of yttria partially stabilized zirconia and air/LSM (Lanthanum strontium manganite) reference electrode. Sieverts’ constant of the dissolved oxygen in LBE was measured from 598 to 748 K by coulometric titration method using the oxygen sensor. The measured oxygen partial pressure in oxygen saturated LBE (PO2(LBE−PbO) in bar) and Sieverts’ constant of dissolved oxygen in LBE (k for 1 wt.% standard state) are given by log PO2(LBE−PbO) = 11.52 − 22996/T (475-724 K), log k = 3.12 − 7072/T (598-748 K) respectively. Combining the measured data, the oxygen solubility in LBE (CO,S in wt.%) was derived and it is given by logCO,S = 2.64 − 4426/T (598-724 K).

KW - LBE

KW - oxygen solubility

UR - http://ecm.sckcen.be/OTCS/llisapi.dll/open/29508488

U2 - 10.1149/2.0231712jes

DO - 10.1149/2.0231712jes

M3 - Article

SN - 0013-4651

VL - 164

SP - H743-H747

JO - Journal of The Electrochemical Society

JF - Journal of The Electrochemical Society

IS - 12

ER -