Gamma irradiation polymerization of isobutème and beta-propiolactone at low temperature

C.  David; F.  Provoost; G. Verduyn

Gamma irradiation polymerization of isobutème and beta-propiolactone at low temperature

C. David, F. Provoost, G. Verduyn

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Abstract

It has been shown that ionic oxides only slightly modify the rate and molecular weight for the solid state polymerization of β-propiolactone and isobutene whereas the effect is much larger in the liquid phase. Resistance measurements of the pure monomers during solid state polymerization have been made. The possibility of an ionic mechanism of polymerization according to the model proposed by fowler is discussed to explain conductivity induced in polymers by ionizing radiation.

Original language	English
Publisher	SCK CEN
Number of pages	12
State	Published - Oct 1962
Externally published	Yes

Publication series

Name	SCK CEN Reports
Publisher	SCK CEN
No.	BLG-291

Cite this

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abstract = "It has been shown that ionic oxides only slightly modify the rate and molecular weight for the solid state polymerization of β-propiolactone and isobutene whereas the effect is much larger in the liquid phase. Resistance measurements of the pure monomers during solid state polymerization have been made. The possibility of an ionic mechanism of polymerization according to the model proposed by fowler is discussed to explain conductivity induced in polymers by ionizing radiation.",

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AU - Provoost, F.

AU - Verduyn, G.

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N2 - It has been shown that ionic oxides only slightly modify the rate and molecular weight for the solid state polymerization of β-propiolactone and isobutene whereas the effect is much larger in the liquid phase. Resistance measurements of the pure monomers during solid state polymerization have been made. The possibility of an ionic mechanism of polymerization according to the model proposed by fowler is discussed to explain conductivity induced in polymers by ionizing radiation.

AB - It has been shown that ionic oxides only slightly modify the rate and molecular weight for the solid state polymerization of β-propiolactone and isobutene whereas the effect is much larger in the liquid phase. Resistance measurements of the pure monomers during solid state polymerization have been made. The possibility of an ionic mechanism of polymerization according to the model proposed by fowler is discussed to explain conductivity induced in polymers by ionizing radiation.

UR - https://ecm.sckcen.be/OTCS/llisapi.dll/overview/39076401

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T3 - SCK CEN Reports

BT - Gamma irradiation polymerization of isobutème and beta-propiolactone at low temperature

PB - SCK CEN

ER -