High‑temperature corrosion behavior of Fe‑18Ni‑12Cr‑2.9Al and Fe‑18Ni‑12Cr‑2.3Al‑Nb‑C austenitic steels depending on dissolved oxygen concentration in static liquid Pb at 700 °C

Valentyn Tsisar; Zhangjian Zhou; Olaf Wedemeyer; Aleksandr Skrypnik; Jürgen Konys; Carsten Schroer

doi:10.1007/s11085-024-10233-2

High‑temperature corrosion behavior of Fe‑18Ni‑12Cr‑2.9Al and Fe‑18Ni‑12Cr‑2.3Al‑Nb‑C austenitic steels depending on dissolved oxygen concentration in static liquid Pb at 700 °C

Valentyn Tsisar, Zhangjian Zhou, Olaf Wedemeyer, Aleksandr Skrypnik, Jürgen Konys, Carsten Schroer

Research output › peer-review

Abstract

The corrosion behavior of the aluminum-alloyed austenitic steels Fe-18Ni-12Cr-2.9Al and Fe-18Ni-12Cr-2.3Al-Nb-C was investigated at 700 °C in static Pb for 1000 h as a function of the concentration of dissolved oxygen in the liquid metal. In Pb with ~ 5 × 10 ^–9 mass % dissolved oxygen, both steels showed dissolution. Depth of corrosion averaged 67 (± 18) µm and 78 (± 25) µm for Fe-18Ni-12Cr-2.3Al-Nb-C and Fe-18Ni-12Cr-2.9Al, respectively. In Pb with higher oxidation potential of 2 × 10 ^–6 mass %O, both steels showed protective and accelerated oxidation. The protective thin oxide film (≤ 1 µm) was composed of outermost Fe-rich, intermediate Cr-rich and inner Al-rich sublayers. The thicker oxide scale was of irregular thickness (2 ÷ 30 µm) and consisted of Fe–Cr mixed oxide with Ni-rich metallic inclusions.

Original language	English
Pages (from-to)	589-602
Number of pages	14
Journal	High Temperature Corrosion of Materials
Volume	101
Issue number	3
DOIs	https://doi.org/10.1007/s11085-024-10233-2
State	Published - Jun 2024

Funding

Funders	Funder number
KIT - Karlsruhe Institute of Technology

ASJC Scopus subject areas

Metals and Alloys
Materials Chemistry
Inorganic Chemistry
Materials Science (miscellaneous)

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10.1007/s11085-024-10233-2License: Unspecified

Cite this

Tsisar, V., Zhou, Z., Wedemeyer, O., Skrypnik, A., Konys, J., & Schroer, C. (2024). High‑temperature corrosion behavior of Fe‑18Ni‑12Cr‑2.9Al and Fe‑18Ni‑12Cr‑2.3Al‑Nb‑C austenitic steels depending on dissolved oxygen concentration in static liquid Pb at 700 °C. High Temperature Corrosion of Materials, 101(3), 589-602. https://doi.org/10.1007/s11085-024-10233-2

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title = "High‑temperature corrosion behavior of Fe‑18Ni‑12Cr‑2.9Al and Fe‑18Ni‑12Cr‑2.3Al‑Nb‑C austenitic steels depending on dissolved oxygen concentration in static liquid Pb at 700 °C",

abstract = "The corrosion behavior of the aluminum-alloyed austenitic steels Fe-18Ni-12Cr-2.9Al and Fe-18Ni-12Cr-2.3Al-Nb-C was investigated at 700 °C in static Pb for 1000 h as a function of the concentration of dissolved oxygen in the liquid metal. In Pb with ~ 5 × 10 –9 mass % dissolved oxygen, both steels showed dissolution. Depth of corrosion averaged 67 (± 18) µm and 78 (± 25) µm for Fe-18Ni-12Cr-2.3Al-Nb-C and Fe-18Ni-12Cr-2.9Al, respectively. In Pb with higher oxidation potential of 2 × 10 –6 mass %O, both steels showed protective and accelerated oxidation. The protective thin oxide film (≤ 1 µm) was composed of outermost Fe-rich, intermediate Cr-rich and inner Al-rich sublayers. The thicker oxide scale was of irregular thickness (2 ÷ 30 µm) and consisted of Fe–Cr mixed oxide with Ni-rich metallic inclusions.",

keywords = "Lead, Steel, Corrosion, Oxidation, Dissolution",

author = "Valentyn Tsisar and Zhangjian Zhou and Olaf Wedemeyer and Aleksandr Skrypnik and J{\"u}rgen Konys and Carsten Schroer",

note = "Score=10 Publisher Copyright: {\textcopyright} The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024.",

year = "2024",

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doi = "10.1007/s11085-024-10233-2",

language = "English",

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Tsisar, V, Zhou, Z, Wedemeyer, O, Skrypnik, A, Konys, J & Schroer, C 2024, 'High‑temperature corrosion behavior of Fe‑18Ni‑12Cr‑2.9Al and Fe‑18Ni‑12Cr‑2.3Al‑Nb‑C austenitic steels depending on dissolved oxygen concentration in static liquid Pb at 700 °C', High Temperature Corrosion of Materials, vol. 101, no. 3, pp. 589-602. https://doi.org/10.1007/s11085-024-10233-2

High‑temperature corrosion behavior of Fe‑18Ni‑12Cr‑2.9Al and Fe‑18Ni‑12Cr‑2.3Al‑Nb‑C austenitic steels depending on dissolved oxygen concentration in static liquid Pb at 700 °C. / Tsisar, Valentyn; Zhou, Zhangjian; Wedemeyer, Olaf et al.
In: High Temperature Corrosion of Materials, Vol. 101, No. 3, 06.2024, p. 589-602.

Research output › peer-review

TY - JOUR

T1 - High‑temperature corrosion behavior of Fe‑18Ni‑12Cr‑2.9Al and Fe‑18Ni‑12Cr‑2.3Al‑Nb‑C austenitic steels depending on dissolved oxygen concentration in static liquid Pb at 700 °C

AU - Tsisar, Valentyn

AU - Zhou, Zhangjian

AU - Wedemeyer, Olaf

AU - Skrypnik, Aleksandr

AU - Konys, Jürgen

AU - Schroer, Carsten

N1 - Score=10 Publisher Copyright: © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024.

PY - 2024/6

Y1 - 2024/6

N2 - The corrosion behavior of the aluminum-alloyed austenitic steels Fe-18Ni-12Cr-2.9Al and Fe-18Ni-12Cr-2.3Al-Nb-C was investigated at 700 °C in static Pb for 1000 h as a function of the concentration of dissolved oxygen in the liquid metal. In Pb with ~ 5 × 10 –9 mass % dissolved oxygen, both steels showed dissolution. Depth of corrosion averaged 67 (± 18) µm and 78 (± 25) µm for Fe-18Ni-12Cr-2.3Al-Nb-C and Fe-18Ni-12Cr-2.9Al, respectively. In Pb with higher oxidation potential of 2 × 10 –6 mass %O, both steels showed protective and accelerated oxidation. The protective thin oxide film (≤ 1 µm) was composed of outermost Fe-rich, intermediate Cr-rich and inner Al-rich sublayers. The thicker oxide scale was of irregular thickness (2 ÷ 30 µm) and consisted of Fe–Cr mixed oxide with Ni-rich metallic inclusions.

AB - The corrosion behavior of the aluminum-alloyed austenitic steels Fe-18Ni-12Cr-2.9Al and Fe-18Ni-12Cr-2.3Al-Nb-C was investigated at 700 °C in static Pb for 1000 h as a function of the concentration of dissolved oxygen in the liquid metal. In Pb with ~ 5 × 10 –9 mass % dissolved oxygen, both steels showed dissolution. Depth of corrosion averaged 67 (± 18) µm and 78 (± 25) µm for Fe-18Ni-12Cr-2.3Al-Nb-C and Fe-18Ni-12Cr-2.9Al, respectively. In Pb with higher oxidation potential of 2 × 10 –6 mass %O, both steels showed protective and accelerated oxidation. The protective thin oxide film (≤ 1 µm) was composed of outermost Fe-rich, intermediate Cr-rich and inner Al-rich sublayers. The thicker oxide scale was of irregular thickness (2 ÷ 30 µm) and consisted of Fe–Cr mixed oxide with Ni-rich metallic inclusions.

KW - Lead

KW - Steel

KW - Corrosion

KW - Oxidation

KW - Dissolution

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DO - 10.1007/s11085-024-10233-2

M3 - Article

SN - 2731-8400

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JO - High Temperature Corrosion of Materials

JF - High Temperature Corrosion of Materials

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