Ion-exchange properties of Zirconium and Titanium phosphates and their use in the separation of nuclear reaction products

Leon Baetslé; I. Markl-Musyl; Daniel Huys

Ion-exchange properties of Zirconium and Titanium phosphates and their use in the separation of nuclear reaction products

Leon Baetslé, I. Markl-Musyl, Daniel Huys

Research output › peer-review

Abstract

Mixtures of 227Ac, 228Th and 226Ra in nitric acid solution were separated by passing through a zirconium phosphate column followed by a titanium phosphate column. The mechanism of ion exchange on TiP was therefore investigated. Distribution coefficients of various ions on TiP were found as a function of molarity of the nitric acid solution and an explanation of the observed selectivity is given. A study of the ion-exchange adsorption of the Th(IV) ion showed it to be adsorbed by TiP as a complex species.

Original language	English
Title of host publication	Ion exchange in the process industries
Subtitle of host publication	Papers read at the conference held at Imperial College of Science and Technology London, 16.-18. July, 1969 with discussions that followed
Editors	G.R. Hall
Publisher	Society of Chemical Industry
Pages	209-214
Number of pages	6
ISBN (Print)	0901001074, 9780901001078
State	Published - 16 Jul 1969
Event	1969 - Ion-exchange in the process industries - Imperial College of Science and Technology, London Duration: 16 Jul 1969 → 18 Jul 1969

Conference

Conference	1969 - Ion-exchange in the process industries
Country/Territory	United Kingdom
City	London
Period	1969-07-16 → 1969-07-18

Cite this

Baetslé, L., Markl-Musyl, I., & Huys, D. (1969). Ion-exchange properties of Zirconium and Titanium phosphates and their use in the separation of nuclear reaction products. In G. R. Hall (Ed.), Ion exchange in the process industries: Papers read at the conference held at Imperial College of Science and Technology London, 16.-18. July, 1969 with discussions that followed (pp. 209-214). Society of Chemical Industry.

Baetslé, Leon ; Markl-Musyl, I. ; Huys, Daniel. / Ion-exchange properties of Zirconium and Titanium phosphates and their use in the separation of nuclear reaction products. Ion exchange in the process industries: Papers read at the conference held at Imperial College of Science and Technology London, 16.-18. July, 1969 with discussions that followed. editor / G.R. Hall. Society of Chemical Industry, 1969. pp. 209-214

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title = "Ion-exchange properties of Zirconium and Titanium phosphates and their use in the separation of nuclear reaction products",

abstract = "Mixtures of 227Ac, 228Th and 226Ra in nitric acid solution were separated by passing through a zirconium phosphate column followed by a titanium phosphate column. The mechanism of ion exchange on TiP was therefore investigated. Distribution coefficients of various ions on TiP were found as a function of molarity of the nitric acid solution and an explanation of the observed selectivity is given. A study of the ion-exchange adsorption of the Th(IV) ion showed it to be adsorbed by TiP as a complex species. ",

keywords = "ion-exchange, Zirconium, Titanum, Phosphates, Separation techniques",

author = "Leon Baetsl{\'e} and I. Markl-Musyl and Daniel Huys",

year = "1969",

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editor = "G.R. Hall",

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note = "1969 - Ion-exchange in the process industries ; Conference date: 16-07-1969 Through 18-07-1969",

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Baetslé, L, Markl-Musyl, I & Huys, D 1969, Ion-exchange properties of Zirconium and Titanium phosphates and their use in the separation of nuclear reaction products. in GR Hall (ed.), Ion exchange in the process industries: Papers read at the conference held at Imperial College of Science and Technology London, 16.-18. July, 1969 with discussions that followed. Society of Chemical Industry, pp. 209-214, 1969 - Ion-exchange in the process industries, London, United Kingdom, 1969-07-16.

Ion-exchange properties of Zirconium and Titanium phosphates and their use in the separation of nuclear reaction products. / Baetslé, Leon; Markl-Musyl, I.; Huys, Daniel.
Ion exchange in the process industries: Papers read at the conference held at Imperial College of Science and Technology London, 16.-18. July, 1969 with discussions that followed. ed. / G.R. Hall. Society of Chemical Industry, 1969. p. 209-214.

Research output › peer-review

TY - GEN

T1 - Ion-exchange properties of Zirconium and Titanium phosphates and their use in the separation of nuclear reaction products

AU - Baetslé, Leon

AU - Markl-Musyl, I.

AU - Huys, Daniel

PY - 1969/7/16

Y1 - 1969/7/16

N2 - Mixtures of 227Ac, 228Th and 226Ra in nitric acid solution were separated by passing through a zirconium phosphate column followed by a titanium phosphate column. The mechanism of ion exchange on TiP was therefore investigated. Distribution coefficients of various ions on TiP were found as a function of molarity of the nitric acid solution and an explanation of the observed selectivity is given. A study of the ion-exchange adsorption of the Th(IV) ion showed it to be adsorbed by TiP as a complex species.

AB - Mixtures of 227Ac, 228Th and 226Ra in nitric acid solution were separated by passing through a zirconium phosphate column followed by a titanium phosphate column. The mechanism of ion exchange on TiP was therefore investigated. Distribution coefficients of various ions on TiP were found as a function of molarity of the nitric acid solution and an explanation of the observed selectivity is given. A study of the ion-exchange adsorption of the Th(IV) ion showed it to be adsorbed by TiP as a complex species.

KW - ion-exchange

KW - Zirconium

KW - Titanum

KW - Phosphates

KW - Separation techniques

UR - https://ecm.sckcen.be/OTCS/llisapi.dll/overview/51806835

M3 - In-proceedings paper

SN - 0901001074

SN - 9780901001078

SP - 209

EP - 214

BT - Ion exchange in the process industries

A2 - Hall, G.R.

PB - Society of Chemical Industry

T2 - 1969 - Ion-exchange in the process industries

Y2 - 16 July 1969 through 18 July 1969

ER -

Baetslé L, Markl-Musyl I, Huys D. Ion-exchange properties of Zirconium and Titanium phosphates and their use in the separation of nuclear reaction products. In Hall GR, editor, Ion exchange in the process industries: Papers read at the conference held at Imperial College of Science and Technology London, 16.-18. July, 1969 with discussions that followed. Society of Chemical Industry. 1969. p. 209-214