TY - JOUR
T1 - Ion-exchange properties of zirconyl phosphates-III. Influence of temperature on tracer ion equilibria
AU - Baetslé, L.
PY - 1963/4
Y1 - 1963/4
N2 - The influence of temperature on the ion exchange reactions of zirconyl phosphate in the H+ form with Rb, Cs, Ca, Sr, Ce and Eu has been studied. It appears that Rb and Cs are very strongly adsorbed at room temperature but easily eluted at 80-100°C. The other nuclides investigated do not show such properties. The thermodynamic quantities ΔG, ΔH and ΔS of the reactions are derived and throw some light on the exchange mechanism of the different ions studied, particularly of the alkali metal ions.
AB - The influence of temperature on the ion exchange reactions of zirconyl phosphate in the H+ form with Rb, Cs, Ca, Sr, Ce and Eu has been studied. It appears that Rb and Cs are very strongly adsorbed at room temperature but easily eluted at 80-100°C. The other nuclides investigated do not show such properties. The thermodynamic quantities ΔG, ΔH and ΔS of the reactions are derived and throw some light on the exchange mechanism of the different ions studied, particularly of the alkali metal ions.
UR - http://www.scopus.com/inward/record.url?scp=0001012418&partnerID=8YFLogxK
U2 - 10.1016/0022-1902(63)80053-6
DO - 10.1016/0022-1902(63)80053-6
M3 - Article
AN - SCOPUS:0001012418
SN - 0022-1902
VL - 25
SP - 271
EP - 282
JO - Journal of Inorganic and Nuclear Chemistry
JF - Journal of Inorganic and Nuclear Chemistry
IS - 3
ER -