Multiphoton dissociation of cf3c1 and cf3 rr under co2 laser pulses

M. Nève De Méverqnies

doi:10.1117/12.938930

Multiphoton dissociation of cf₃c1 and cf₃ rr under co₂ laser pulses

M. Nève De Méverqnies

Research output › peer-review

Abstract

Multiphoton dissociation of CF₃C1 and CF₃ Br induced by CO₂ laser pulses has been studied in the (0.1 - 60 torr) pressure ranqe and (5 - 30 Jou.le/cm²) averaqe enerqy density ranae. The laser was adjusted on 1071.9 cm^-1 and 1052.2 cm^-1, resp., so as to excite preferentially the¹³C isotopic molecules. The effects of pressure and energy on the isotopic selectivity were measured and a remarkable difference was found between the two molecules. As for the dissociation probabilities, they vary exponentially with the inverse of the enerqy. The applicability of such an Arrhenius-type relation is discussed and semi-guantitatively justified.

Original language	English
Pages (from-to)	26-33
Number of pages	8
Journal	Proceedings of SPIE - The International Society for Optical Engineering
Volume	669
DOIs	https://doi.org/10.1117/12.938930
State	Published - 25 Nov 1986
Externally published	Yes

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Computer Science Applications
Applied Mathematics
Electrical and Electronic Engineering

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10.1117/12.938930

Cite this

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title = "Multiphoton dissociation of cf3c1 and cf3 rr under co2 laser pulses",

abstract = "Multiphoton dissociation of CF3C1 and CF3 Br induced by CO2 laser pulses has been studied in the (0.1 - 60 torr) pressure ranqe and (5 - 30 Jou.le/cm2) averaqe enerqy density ranae. The laser was adjusted on 1071.9 cm-1 and 1052.2 cm-1, resp., so as to excite preferentially the13C isotopic molecules. The effects of pressure and energy on the isotopic selectivity were measured and a remarkable difference was found between the two molecules. As for the dissociation probabilities, they vary exponentially with the inverse of the enerqy. The applicability of such an Arrhenius-type relation is discussed and semi-guantitatively justified.",

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N2 - Multiphoton dissociation of CF3C1 and CF3 Br induced by CO2 laser pulses has been studied in the (0.1 - 60 torr) pressure ranqe and (5 - 30 Jou.le/cm2) averaqe enerqy density ranae. The laser was adjusted on 1071.9 cm-1 and 1052.2 cm-1, resp., so as to excite preferentially the13C isotopic molecules. The effects of pressure and energy on the isotopic selectivity were measured and a remarkable difference was found between the two molecules. As for the dissociation probabilities, they vary exponentially with the inverse of the enerqy. The applicability of such an Arrhenius-type relation is discussed and semi-guantitatively justified.

AB - Multiphoton dissociation of CF3C1 and CF3 Br induced by CO2 laser pulses has been studied in the (0.1 - 60 torr) pressure ranqe and (5 - 30 Jou.le/cm2) averaqe enerqy density ranae. The laser was adjusted on 1071.9 cm-1 and 1052.2 cm-1, resp., so as to excite preferentially the13C isotopic molecules. The effects of pressure and energy on the isotopic selectivity were measured and a remarkable difference was found between the two molecules. As for the dissociation probabilities, they vary exponentially with the inverse of the enerqy. The applicability of such an Arrhenius-type relation is discussed and semi-guantitatively justified.

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