TY - JOUR
T1 - Numerical simulation of transport and sequential biodegradation of chlorinated aliphatic hydrocarbons using CHAIN_2D
AU - Schaerlaekens, Jan
AU - Mallants, D.
AU - Šimûnek, J.
AU - Van Genuchten, M. Th
AU - Feyen, J.
PY - 1999/12/15
Y1 - 1999/12/15
N2 - Microbiological degradation of perchloroethylene (PCE) under anaerobic conditions follows a series of chain reactions, in which, sequentially, trichloroethylene (TCE), cis-dichloroethylene (c-DCE), vinylchloride (VC) and ethene are generated. First-order degradation rate constants, partitioning coefficients and mass exchange rates for PCE, TCE, c-DCE and VC were compiled from the literature. The parameters were used in a case study of pump-and-treat remediation of a PCE-contaminated site near Tilburg. The Netherlands. Transport, non-equilibrium sorption and biodegradation chain processes at the site were simulated using the CHAIN_2D code without further calibration. The modelled PCE compared reasonably well with observed PCE concentrations in the pumped water. We also performed a scenario analysis by applying several increased reductive dechlorination rates, reflecting different degradation conditions (e.g. addition of yeast extract and citrate). The scenario analysis predicted considerably higher concentrations of the degradation products as a result of enhanced reductive dechlorination of PCE. The predicted levels of the very toxic compound VC were now an order of magnitude above the maximum permissible concentration levels.
AB - Microbiological degradation of perchloroethylene (PCE) under anaerobic conditions follows a series of chain reactions, in which, sequentially, trichloroethylene (TCE), cis-dichloroethylene (c-DCE), vinylchloride (VC) and ethene are generated. First-order degradation rate constants, partitioning coefficients and mass exchange rates for PCE, TCE, c-DCE and VC were compiled from the literature. The parameters were used in a case study of pump-and-treat remediation of a PCE-contaminated site near Tilburg. The Netherlands. Transport, non-equilibrium sorption and biodegradation chain processes at the site were simulated using the CHAIN_2D code without further calibration. The modelled PCE compared reasonably well with observed PCE concentrations in the pumped water. We also performed a scenario analysis by applying several increased reductive dechlorination rates, reflecting different degradation conditions (e.g. addition of yeast extract and citrate). The scenario analysis predicted considerably higher concentrations of the degradation products as a result of enhanced reductive dechlorination of PCE. The predicted levels of the very toxic compound VC were now an order of magnitude above the maximum permissible concentration levels.
KW - Biodegradation
KW - Chlorinated aliphatic hydrocarbons (CAH's)
KW - Numerical modelling
KW - Sorption
KW - Transport
UR - http://www.scopus.com/inward/record.url?scp=0033572460&partnerID=8YFLogxK
U2 - 10.1002/(SICI)1099-1085(19991215)13:17<2847::AID-HYP903>3.0.CO;2-M
DO - 10.1002/(SICI)1099-1085(19991215)13:17<2847::AID-HYP903>3.0.CO;2-M
M3 - Article
AN - SCOPUS:0033572460
SN - 0885-6087
VL - 13
SP - 2847
EP - 2859
JO - Hydrological Processes
JF - Hydrological Processes
IS - 17
ER -