Oxygen-iron interaction in liquid lead-bismuth eutectic alloy

Alexander Aerts; Serguei Gavrilov; Gabriele Manfredi; Alessandro Marino; Kris Rosseel; Jun Lim

doi:10.1039/C6CP01561A

Oxygen-iron interaction in liquid lead-bismuth eutectic alloy

Alexander Aerts, Serguei Gavrilov, Gabriele Manfredi, Alessandro Marino, Kris Rosseel, Jun Lim

Conditioning and Chemistry Programme

Research output › peer-review

Abstract

Iron released by steel corrosion was found to be a key impurity in reactions with dissolved oxygen in liquid lead-bismuth eutectic alloy. The iron-oxygen-magnetite equilibrium was characterized, allowing quantification of phenomena that are important for long- term operation of lead-alloy based installations such as corrosion rate control and management of precipitates.

Original language	English
Pages (from-to)	19526-19530
Journal	PCCP - Physical Chemistry Chemical Physics
Volume	18
Issue number	29
DOIs	https://doi.org/10.1039/C6CP01561A
State	Published - 30 Jun 2016

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Cite this

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title = "Oxygen-iron interaction in liquid lead-bismuth eutectic alloy",

abstract = "Iron released by steel corrosion was found to be a key impurity in reactions with dissolved oxygen in liquid lead-bismuth eutectic alloy. The iron-oxygen-magnetite equilibrium was characterized, allowing quantification of phenomena that are important for long- term operation of lead-alloy based installations such as corrosion rate control and management of precipitates.",

keywords = "lead bismuth eutectic, liquid lead alloys, magnetite, Corrosion",

author = "Alexander Aerts and Serguei Gavrilov and Gabriele Manfredi and Alessandro Marino and Kris Rosseel and Jun Lim",

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AU - Manfredi, Gabriele

AU - Marino, Alessandro

AU - Rosseel, Kris

AU - Lim, Jun

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AB - Iron released by steel corrosion was found to be a key impurity in reactions with dissolved oxygen in liquid lead-bismuth eutectic alloy. The iron-oxygen-magnetite equilibrium was characterized, allowing quantification of phenomena that are important for long- term operation of lead-alloy based installations such as corrosion rate control and management of precipitates.

KW - lead bismuth eutectic

KW - liquid lead alloys

KW - magnetite

KW - Corrosion

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DO - 10.1039/C6CP01561A

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