Remarks concerning the applicability of an Arrhenius-type relation to infrared multiphoton dissociation processes

M. Nève de Mévergnies

doi:10.1007/BF00692827

Remarks concerning the applicability of an Arrhenius-type relation to infrared multiphoton dissociation processes

M. Nève de Mévergnies

Research output › peer-review

Abstract

It is shown that, in the case of some halomethanes for which an Arrhenius-type relation can be fitted to the IRMPD probabilities as a function of CO₂-laser pulse energy, the pre-exponential factor is about equal to the ratio of the reaction volume to the total gas volume.

Original language	English
Pages (from-to)	123-126
Number of pages	4
Journal	Applied Physics B Photophysics and Laser Chemistry
Volume	43
Issue number	2
DOIs	https://doi.org/10.1007/BF00692827
State	Published - Jun 1987

ASJC Scopus subject areas

General Engineering

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10.1007/BF00692827

Cite this

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title = "Remarks concerning the applicability of an Arrhenius-type relation to infrared multiphoton dissociation processes",

abstract = "It is shown that, in the case of some halomethanes for which an Arrhenius-type relation can be fitted to the IRMPD probabilities as a function of CO2-laser pulse energy, the pre-exponential factor is about equal to the ratio of the reaction volume to the total gas volume.",

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AB - It is shown that, in the case of some halomethanes for which an Arrhenius-type relation can be fitted to the IRMPD probabilities as a function of CO2-laser pulse energy, the pre-exponential factor is about equal to the ratio of the reaction volume to the total gas volume.

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JO - Applied Physics B Photophysics and Laser Chemistry

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