Shape of emission bands of fluorescent complex molecules

H. Voorhof; H. Pollak

doi:10.1063/1.1727370

Shape of emission bands of fluorescent complex molecules

H. Voorhof, H. Pollak

Research output › peer-review

Abstract

The shape of emission bands is determined by the vibrational-energy distribution of the luminescence centers and by the form of the potential curves. A new potential is introduced, permitting us to establish the intensity distribution within a band as a function of frequency and temperature. The calculations are based on a semiclassical approximation of the Franck-Condon factors and are worked out with the aid of the Mehler formula. The obtained expression is in close agreement with the experimental results.

Original language	English
Pages (from-to)	3542-3545
Number of pages	4
Journal	The Journal of Chemical Physics
Volume	45
Issue number	10
DOIs	https://doi.org/10.1063/1.1727370
State	Published - 1966

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

Access to Document

10.1063/1.1727370

Cite this

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title = "Shape of emission bands of fluorescent complex molecules",

abstract = "The shape of emission bands is determined by the vibrational-energy distribution of the luminescence centers and by the form of the potential curves. A new potential is introduced, permitting us to establish the intensity distribution within a band as a function of frequency and temperature. The calculations are based on a semiclassical approximation of the Franck-Condon factors and are worked out with the aid of the Mehler formula. The obtained expression is in close agreement with the experimental results.",

author = "H. Voorhof and H. Pollak",

year = "1966",

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AU - Pollak, H.

PY - 1966

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N2 - The shape of emission bands is determined by the vibrational-energy distribution of the luminescence centers and by the form of the potential curves. A new potential is introduced, permitting us to establish the intensity distribution within a band as a function of frequency and temperature. The calculations are based on a semiclassical approximation of the Franck-Condon factors and are worked out with the aid of the Mehler formula. The obtained expression is in close agreement with the experimental results.

AB - The shape of emission bands is determined by the vibrational-energy distribution of the luminescence centers and by the form of the potential curves. A new potential is introduced, permitting us to establish the intensity distribution within a band as a function of frequency and temperature. The calculations are based on a semiclassical approximation of the Franck-Condon factors and are worked out with the aid of the Mehler formula. The obtained expression is in close agreement with the experimental results.

UR - https://www.scopus.com/pages/publications/36849111353

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DO - 10.1063/1.1727370

M3 - Article

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SN - 0021-9606

VL - 45

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EP - 3545

JO - The Journal of Chemical Physics

JF - The Journal of Chemical Physics

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