Surface conditioning of a sodium β-alumina based lithium sensor for lithium-lead blends

F. De Schutter; Ja Dekeyser; R. Deknock; R. Jacobs; H. Tas

doi:10.1016/0167-2738(90)90113-6

Surface conditioning of a sodium β-alumina based lithium sensor for lithium-lead blends

F. De Schutter
, Ja Dekeyser
, R. Deknock
, R. Jacobs
, H. Tas

Research output › peer-review

Abstract

The impedance of a sodium β-alumina based electrochemical sensor, developed for the determination of the lithium activity in liquid metal blends, was investigated as a function of temperature. The impedance spectra could be rationalised in terms of purely resistive bulk conduction, dispersive grain boundary conduction and a diffusion-limited electrode conduction. Values of log (T/ R), as derived from the interior grain and grain boundary resistivities were found to follow an Arrhenius behaviour. Corresponding activation energies of respectively 30 and 58 kcal/mol were calculated.

Original language	English
Pages (from-to)	754-757
Number of pages	4
Journal	Solid State Ionics
Volume	40-41
Issue number	PART 2
DOIs	https://doi.org/10.1016/0167-2738(90)90113-6
State	Published - Aug 1990

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

Access to Document

10.1016/0167-2738(90)90113-6

Cite this

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title = "Surface conditioning of a sodium β-alumina based lithium sensor for lithium-lead blends",

abstract = "The impedance of a sodium β-alumina based electrochemical sensor, developed for the determination of the lithium activity in liquid metal blends, was investigated as a function of temperature. The impedance spectra could be rationalised in terms of purely resistive bulk conduction, dispersive grain boundary conduction and a diffusion-limited electrode conduction. Values of log (T/ R), as derived from the interior grain and grain boundary resistivities were found to follow an Arrhenius behaviour. Corresponding activation energies of respectively 30 and 58 kcal/mol were calculated.",

author = "\{De Schutter\}, F. and Ja Dekeyser and R. Deknock and R. Jacobs and H. Tas",

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AU - Dekeyser, Ja

AU - Deknock, R.

AU - Jacobs, R.

AU - Tas, H.

PY - 1990/8

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N2 - The impedance of a sodium β-alumina based electrochemical sensor, developed for the determination of the lithium activity in liquid metal blends, was investigated as a function of temperature. The impedance spectra could be rationalised in terms of purely resistive bulk conduction, dispersive grain boundary conduction and a diffusion-limited electrode conduction. Values of log (T/ R), as derived from the interior grain and grain boundary resistivities were found to follow an Arrhenius behaviour. Corresponding activation energies of respectively 30 and 58 kcal/mol were calculated.

AB - The impedance of a sodium β-alumina based electrochemical sensor, developed for the determination of the lithium activity in liquid metal blends, was investigated as a function of temperature. The impedance spectra could be rationalised in terms of purely resistive bulk conduction, dispersive grain boundary conduction and a diffusion-limited electrode conduction. Values of log (T/ R), as derived from the interior grain and grain boundary resistivities were found to follow an Arrhenius behaviour. Corresponding activation energies of respectively 30 and 58 kcal/mol were calculated.

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DO - 10.1016/0167-2738(90)90113-6

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