The controlled oxidation of single crystals of UO2 to U4O9

W. Van Lierde, L. De Jonghe

Research outputpeer-review

Abstract

A simple and reliable method is presented for the controlled oxidation of UO2 which allows the preparation of single crystals with a composition between UO2 and U4O9 starting from a stoichiometric crystal. The principle of the method is the equilibration of the oxygen dissociation pressures of UO2 and U3O8 heated together in vacuum. The practical applications are shown.

Original languageEnglish
Pages (from-to)129-131
Number of pages3
JournalSolid State Communications
Volume2
Issue number5
DOIs
StatePublished - May 1964
Externally publishedYes

ASJC Scopus subject areas

  • General Chemistry
  • Condensed Matter Physics
  • Materials Chemistry

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