TY - JOUR
T1 - The effect of Vickers hardness indentations on the fracture mode in 8 mol% yttria-stabilised zirconia
AU - Vandermeulen, Willy
AU - Bosch, Rik-Wouter
AU - Snijkers, Frans
A2 - Gavrilov, Serguei
N1 - Score = 10
PY - 2015/4
Y1 - 2015/4
N2 - Cubic 8 mol% Y2O3-stabilised ZrO2 is well known for its good oxygen conductivity and therefore it is used in fuel cells, as oxygen sensor for liquid metals and as pH sensor in high temperature water. As a part of its fracture toughness assessment, the crack system caused by Vickers hardness indentations was examined by breaking specimens along an indentation diagonal. It was found that, although the normally observed fracture mode is transgranular, intergranular fracture occurred in the zone below an indentation. Annealing the specimen above 900 C before breaking caused the disappearance of this effect.
The intergranular fracture mode was explained by the
combined effect of plastic deformation under the indentation
and environmental humidity. Annealing is expected to
cause restoration to the un-deformed structure. Observations
on the intergranular and transgranular cracking pattern,
slow crack growth occurrence and step formation at
the fracture surface, are reported.
AB - Cubic 8 mol% Y2O3-stabilised ZrO2 is well known for its good oxygen conductivity and therefore it is used in fuel cells, as oxygen sensor for liquid metals and as pH sensor in high temperature water. As a part of its fracture toughness assessment, the crack system caused by Vickers hardness indentations was examined by breaking specimens along an indentation diagonal. It was found that, although the normally observed fracture mode is transgranular, intergranular fracture occurred in the zone below an indentation. Annealing the specimen above 900 C before breaking caused the disappearance of this effect.
The intergranular fracture mode was explained by the
combined effect of plastic deformation under the indentation
and environmental humidity. Annealing is expected to
cause restoration to the un-deformed structure. Observations
on the intergranular and transgranular cracking pattern,
slow crack growth occurrence and step formation at
the fracture surface, are reported.
KW - YSZ sensors
KW - hardness indentations
KW - intergranular fracture
UR - http://ecm.sckcen.be/OTCS/llisapi.dll/open/ezp_139900
UR - http://knowledgecentre.sckcen.be/so2/bibref/12803
U2 - 10.1007/s10853-015-8858-7
DO - 10.1007/s10853-015-8858-7
M3 - Article
SN - 0022-2461
VL - 50
SP - 2932
EP - 2943
JO - Journal of Materials Science
JF - Journal of Materials Science
IS - 7
ER -