Thiocyanate complexes of some trivalent lanthandide and actinide elements

G.R. Choppin; Jacques Ketels

Thiocyanate complexes of some trivalent lanthandide and actinide elements

G.R. Choppin, Jacques Ketels

Research output › peer-review

Abstract

The stability constants for the formation of MSCN₂⁺ and M(SCN)₂⁺ where M= Nd(III), EU(III), Pu(III), Am(III), Cm(III), and Cf(III) have been determined using the solvent extraction method and an ionic strength of 1.00 M. The enthalpy and entropy values for the formation of NdSCN²⁺ and AmSCN²⁺ indicate that these complexes are outer sphere ion pairs.

Original language	English
Publisher	SCK CEN
Number of pages	9
State	Published - Oct 1964

Publication series

Name	SCK CEN Reports
Publisher	SCK CEN
No.	BLG-416

Cite this

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title = "Thiocyanate complexes of some trivalent lanthandide and actinide elements",

abstract = "The stability constants for the formation of MSCN2+ and M(SCN)2+ where M= Nd(III), EU(III), Pu(III), Am(III), Cm(III), and Cf(III) have been determined using the solvent extraction method and an ionic strength of 1.00 M. The enthalpy and entropy values for the formation of NdSCN2+ and AmSCN2+ indicate that these complexes are outer sphere ion pairs.",

author = "G.R. Choppin and Jacques Ketels",

year = "1964",

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language = "English",

series = "SCK CEN Reports",

publisher = "SCK CEN",

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AU - Choppin, G.R.

AU - Ketels, Jacques

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N2 - The stability constants for the formation of MSCN2+ and M(SCN)2+ where M= Nd(III), EU(III), Pu(III), Am(III), Cm(III), and Cf(III) have been determined using the solvent extraction method and an ionic strength of 1.00 M. The enthalpy and entropy values for the formation of NdSCN2+ and AmSCN2+ indicate that these complexes are outer sphere ion pairs.

AB - The stability constants for the formation of MSCN2+ and M(SCN)2+ where M= Nd(III), EU(III), Pu(III), Am(III), Cm(III), and Cf(III) have been determined using the solvent extraction method and an ionic strength of 1.00 M. The enthalpy and entropy values for the formation of NdSCN2+ and AmSCN2+ indicate that these complexes are outer sphere ion pairs.

UR - https://ecm.sckcen.be/OTCS/llisapi.dll/overview/39074015

M3 - BLG - Open report

T3 - SCK CEN Reports

BT - Thiocyanate complexes of some trivalent lanthandide and actinide elements

PB - SCK CEN

ER -