Trends in the valence band electronic structures of mixed uranium oxides

Kristina Kvashnina; P.M. Kowalski; S.M. Butorin; Gregory Leinders; Janne Pakarinen; Rene Bes; H. Li; Marc Verwerft

doi:10.1039/c8cc05464a

Trends in the valence band electronic structures of mixed uranium oxides

Kristina Kvashnina, P.M. Kowalski, S.M. Butorin, Gregory Leinders, Janne Pakarinen, Rene Bes, H. Li, Marc Verwerft

Research output › peer-review

Abstract

Valence band electronic structure of mixed uranium oxides (UO2, U4O9, U3O7, U3O8, -UO3) has been studied by the resonant inelastic X-ray scattering (RIXS) technique at the U M5 edge and the computational methods. We show here that the RIXS technique and recorded U 5f - O 2p charge transfer excitations can be used to proof the validity of theoretical aproximations.

Original language	English
Number of pages	4
Journal	Chemical Communications
DOIs	https://doi.org/10.1039/c8cc05464a
State	Published - 8 Aug 2018

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title = "Trends in the valence band electronic structures of mixed uranium oxides",

abstract = "Valence band electronic structure of mixed uranium oxides (UO2, U4O9, U3O7, U3O8, -UO3) has been studied by the resonant inelastic X-ray scattering (RIXS) technique at the U M5 edge and the computational methods. We show here that the RIXS technique and recorded U 5f - O 2p charge transfer excitations can be used to proof the validity of theoretical aproximations.",

keywords = "Valence band electronic structure, Uranium oxides, RIXS, ESRF",

author = "Kristina Kvashnina and P.M. Kowalski and S.M. Butorin and Gregory Leinders and Janne Pakarinen and Rene Bes and H. Li and Marc Verwerft",

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AU - Kvashnina, Kristina

AU - Kowalski, P.M.

AU - Butorin, S.M.

AU - Leinders, Gregory

AU - Pakarinen, Janne

AU - Bes, Rene

AU - Li, H.

AU - Verwerft, Marc

N1 - Score=10

PY - 2018/8/8

Y1 - 2018/8/8

N2 - Valence band electronic structure of mixed uranium oxides (UO2, U4O9, U3O7, U3O8, -UO3) has been studied by the resonant inelastic X-ray scattering (RIXS) technique at the U M5 edge and the computational methods. We show here that the RIXS technique and recorded U 5f - O 2p charge transfer excitations can be used to proof the validity of theoretical aproximations.

AB - Valence band electronic structure of mixed uranium oxides (UO2, U4O9, U3O7, U3O8, -UO3) has been studied by the resonant inelastic X-ray scattering (RIXS) technique at the U M5 edge and the computational methods. We show here that the RIXS technique and recorded U 5f - O 2p charge transfer excitations can be used to proof the validity of theoretical aproximations.

KW - Valence band electronic structure

KW - Uranium oxides

KW - RIXS

KW - ESRF

UR - http://ecm.sckcen.be/OTCS/llisapi.dll/open/31274776

U2 - 10.1039/c8cc05464a

DO - 10.1039/c8cc05464a

M3 - Article

SN - 1359-7345

JO - Chemical Communications

JF - Chemical Communications

ER -